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New Images Lead to Better Prediction of Shear Thickening

on a top horizontal row there are two clusters of smooth spheres packed closely together the clusters are separated by a series of closely intertwined lines; on a bottom horizontal row there are two clusters of rough-edged spherical objects packed closely together the clusters are separated by a series of erratic, widely-spaced lines
Renderings of microscopic images obtained from the confocal rheometer, showing the intricate network architectures formed by smooth (top) and rough (bottom) particles in strongly shear thickening suspensions. The clustered particles have been cut away from the center of each image and replaced with blue lines that illustrate the nature of the networks formed between particles.

For Immediate Release

For the first time, researchers have been able capture images providing unprecedented details of how particles behave in a liquid suspension when the phenomenon known as shear thickening takes place. The work allows us to directly understand the processes behind shear thickening, which had previously only been understood based on inference and computational modeling.

Shear thickening is a phenomenon that can occur when particles are suspended in a low-viscosity solution. If the concentration of particles is high enough, then when stress is applied to the solution it becomes very viscous – effectively behaving like a solid. When the stress is removed or dissipates, the suspension returns to its normal fluid-like viscosity. This phenomenon can be seen in popular YouTube videos in which people are able to run across a solution of corn starch suspended in water – but sink into the solution when they stand still.

Shear thickening can be a liability or an advantage, depending on the context.

For example, in industries from food processing to pharmaceutical manufacturing, companies often try to pump liquids with high particle concentrations to make manufacturing processes more efficient and cost-effective. And if those companies don’t properly account for shear thickening, the liquids being pumped can jam or clog – costing them valuable time and potentially damaging their equipment.

On the other hand, the properties of shear thickening can also be used to develop force-absorbing materials for use in applications such as body armor, or as a mechanism for controlling the physical characteristics of soft robotics devices.

For these reasons, researchers have spent years trying to understand precisely how and why shear thickening occurs. However, researchers have been forced to rely on indirect experimentation, because they were unable to capture the precise behavior of the particles in solution as shear thickening takes place. Until now.

A team of researchers at North Carolina State University and Northeastern University used a customized instrument, called a confocal rheometer, to capture microscopic images of particles in solution as they were exposed to stress in order to trigger shear thickening. Computer simulations were used to support the experimental observations.

“As the stress increased, we were able to see complex networks form between particles,” says Lilian Hsiao, corresponding author of a paper on the work and an assistant professor of chemical and biomolecular engineering at NC State. “And the shapes of these networks were dependent on the shape and roughness of the particles. Specifically, the way neighboring particles are rearranged when stress is applied dictates the way they shear thicken.

“Understanding these correlations between particle roughness, large-scale particles, and shear thickening allow us to better predict the shear thickening behavior of suspensions.”

Specifically, the research team developed a way to more accurately predict how much stress can be applied to a given concentration of particles before a suspension begins to experience shear thickening – as well as how viscous the solution will become – based on the roughness of the particles. The roughness of the particles matters because their surface interactions dictate how tightly the particles can be packed together, or “jammed,” in the suspension before becoming effectively solid.

“For practical applications, people won’t need to capture their own microscopy images of what’s happening during the shear thickening process,” Hsiao says. “If they know the roughness of the particles they have in solution, they will be able to determine what concentrations will work for their various applications.”

The paper, “Jamming Distance Dictates Colloidal Shear Thickening,” is published in Physical Review Letters. First author of the paper is Shravan Pradeep, a former Ph.D. student at NC State. The paper was co-authored by Alan Jacob, a former postdoctoral researcher at NC State; Mohammad Nabizadeh, a graduate student at Northeastern; and Safa Jamali, an assistant professor of industrial and mechanical engineering at Northeastern.

The work was done with support from the National Science Foundation, under grants 1804462 and 2104726; and from the American Chemical Society Petroleum Research Fund.

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Note to Editors: The study abstract follows.

“Jamming Distance Dictates Colloidal Shear Thickening”

Authors: Shravan Pradeep, Alan R. Jacob and Lilian C. Hsiao, North Carolina State University; Mohammad Nabizadeh and Safa Jamali, Northeastern University

Published: Oct. 6, Physical Review Letters

DOI: 10.1103/PhysRevLett.127.158002

Abstract: We report experimental and computational observations of dynamic contact networks for colloidal suspensions undergoing shear thickening. The dense suspensions are comprised of sterically stabilized poly(methyl methacrylate) colloids that are spherically symmetric and have varied surface roughness. Confocal rheometry and dissipative particle dynamics simulations show that the shear thickening strength β scales exponentially with the scaled deficit contact number and the scaled jamming distance. Rough colloids, which experience additional rotational constraints, require an average of 1.5–2 fewer particle contacts as compared to smooth colloids, in order to generate the same β. This is because the surface roughness enhances geometric friction in a way that the rough colloids do not experience a large change in the free volume near the jamming point. The available free volume is related to the deficiency from the maximum number of nearest neighbors at jamming under shear. Our results further suggest that the force per contact is different for particles with different morphologies.

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