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New Techniques Stretch Carbon Nanotubes, Make Stronger Composites

Researchers from North Carolina State University have developed new techniques for stretching carbon nanotubes (CNT) and using them to create carbon composites that can be used as stronger, lighter materials in everything from airplanes to bicycles.

By stretching the CNT material before incorporating it into a composite for use in finished products, the researchers straighten the CNTs in the material, which significantly improves its tensile strength – and enhances the stiffness of the composite material and its electrical and thermal conductivity.

Researchers used a rotating spool to create ribbon-like composite material that have a high percentage of carbon nanotubes, for use in products from airplanes to bicycles.

State-of-the-art carbon fiber composites are currently used to build airplanes and other products where strong, lightweight materials are desirable. Lighter airplanes, for example, are more fuel efficient. However, researchers have long thought that if these composites could be made with CNTs they could be just as strong, but 10 times lighter. Or they could be the same weight, but 10 times stronger.

Creating a strong CNT composite requires four features. First, it needs long CNTs, which are more effective at carrying loads. Second, the CNTs need to be aligned in rows. Third, the CNTs in the material are held together by a polymer or resin, and you need to have a high ratio of CNTs to polymer in the finished composite material. Fourth, you need the CNTs to be as straight as possible, so that the material bears weight evenly.

For decades, researchers have been unable to achieve these goals. But now a research team, led by Dr. Yuntian Zhu, a professor of materials science and engineering at NC State, has developed a solution.

“The new technique begins with a CNT array,” Zhu says, “which looks like a forest of CNTs growing up out of a flat substrate.” Because the aspect ratio of these CNTs is high, they are long and skinny – not rigid. That means the CNTs are leaning against each other in the array. “By grabbing the CNTs at one end of the array, we are able to pull them over onto their sides – and all of the other CNTs in the array topple in the same direction,” Zhu says. This results in CNTs with good alignment.

These aligned CNTs are then wound onto a rotating spool and sprayed with a polymer solution to bind the CNTs together. This creates a ribbon-like composite material that has a high percentage of CNTs by volume, which can in turn be used to make CNT composite structures for use in finished products like airplanes and bicycles. But that doesn’t address the need to straighten the CNTs.

To straighten the CNTs, Zhu and his team stretched the CNTs as the nanotubes are being pulled onto the rotating spool. This process improves the tensile strength of the CNT composite “ribbon” by approximately 90 percent (to an average of 3.5 gigapascals) and stiffness by more than 100 percent. By straightening the CNTs, the researchers were also able to almost triple the CNT composite’s thermal conductivity, to 40 watts per meter per kelvin. Electrical conductivity was increased by 50 percent to 1,230 siemens per meter.

The paper on stretching the CNTs to straighten them, “Ultrastrong, Stiff and Multifunctional Films Assembled from Superaligned Carbon Nanotubes,” is published online in the inaugural issue of the journal Materials Research Letters. The research was supported, in part, by the Air Force Office of Scientific Research and the North Carolina Space Grant.

Researchers involved with the work came from NC State, Suzhou Institute of Nano-Tech and Nano-Bionics, Donghua University, Marshall Space Flight Center, Oak Ridge National Laboratory, and Los Alamos National Laboratory.


Note to Editors: The study abstracts follow.

“Ultrastrong, Stiff and Multifunctional Films Assembled from Superaligned Carbon Nanotubes”

Authors: Xin Wang, Philip D. Bradford, Fuh-Gwo Yuan and Yuntian Zhu, North Carolina State University; Zhenzhong Yong, Qingwen Li, Suzhou Institute of Nanot-Tech and Nano-Bionics; Wei Liu, Donghua University; Dennis S. Tucker, Marshall Space Flight Center; Wei Cai, Hsin Wang, Oak Ridge National Laboratory

Published: Online, Oct. 11 2012, Materials Research Letters

Abstract: A novel route is developed for preparing ultrastrong, stiff and thermally and electrically conductive carbon nanotube (CNT) composite films. The free-standing unidirectional films, with controlled thicknesses, are prepared by incorporating superaligned CNTs into polymer matrix via stretch-winding. The obtained CNT composite films exhibit unprecedented multifunctionalities of any known engineering composites, including highest values for tensile strength (3.8 GPa), Young’s modulus (293 GPa), electrical conductivity (1200 S cm-1) and thermal conductivity (40 W m-1 K-1). Such CNT/polymer film can also withstand severe bending and maintain the high electrical conductivity after being bent for 1000 cycles. These superior properties are primarily derived from the long CNT length, high volume fraction, good CNT alignment and reduced waviness of the CNTs. The combination of high strength and excellent thermal and electrical conductivities makes it promising to improve and enable new aerospace technologies and adventures.