Material Would Allow Users to ‘Tune’ Windows to Block Targeted Wavelengths of Light

For Immediate Release

Veronica Augustynvaugust@ncsu.edu

Delia Millironmilliron@che.utexas.edu

Matt Shipmanmatt_shipman@ncsu.edu

Researchers have demonstrated a material for next generation dynamic windows, which would allow building occupants to switch their windows between three modes: transparent, or “normal” windows; windows that block infrared light, helping to keep a building cool; and tinted windows that control glare while maintaining the view.

Dynamic windows based on electrochromism – meaning their opacity changes in response to electric stimulus – are not a new concept. But, to this point, most dynamic windows were either clear or dark.

“Our work demonstrates that there are more options available,” says Veronica Augustyn, co-corresponding author of a paper on the work and the Jake and Jennifer Hooks Distinguished Scholar in Materials Science and Engineering at North Carolina State University. “Specifically, we’ve shown that you can allow light to pass through the windows while still helping to keep buildings cooler and thus more energy efficient.”

The key to more dynamic window materials is water.

Specifically, the researchers found that when water is bound within the crystalline structure of a tungsten oxide – forming tungsten oxide hydrate – the material exhibits a previously unknown behavior.

Tungsten oxides have long been used in dynamic windows. That’s because tungsten oxide is normally transparent. But when you apply an electrical signal, and inject lithium ions and electrons into the material, the material becomes dark and blocks light.

Researchers have now shown that you can effectively tune the wavelengths of light that are blocked when you inject lithium ions and electrons into a related material called tungsten oxide hydrate. When lithium ions and electrons are injected into the hydrate material, it first transitions into a “heat blocking” phase, allowing visible wavelengths of light to pass through, but blocking infrared light. If more lithium ions and electrons are injected, the material then transitions into a dark phase, blocking both visible and infrared wavelengths of light.

“The presence of water in the crystalline structure makes the structure less dense, so the structure is more resistant to deformation when lithium ions and electrons are injected into the material,” says Jenelle Fortunato, first author of the paper and a postdoctoral fellow at NC State. “Our hypothesis is that, because the tungsten oxide hydrate can accommodate more lithium ions than regular tungsten oxide before deforming, you get two modes. There’s a ‘cool’ mode – when injection of lithium ions and electrons affects the optical properties, but structural change hasn’t occurred yet – which absorbs infrared light. And then, after the structural change occurs, there’s a ‘dark’ mode that blocks both visible and infrared light.”

“The discovery of dual-band (infrared and visible) light control in a single material that’s already well-known to the smart windows community may accelerate development of commercial products with enhanced features,” says Delia Milliron, co-corresponding author of the paper and the Ernest Cockrell, Sr. Chair #1 in Engineering at the University of Texas at Austin. “More broadly speaking, the unforeseen role of structural water in producing distinctive electrochemical properties may inspire the research community beyond smart window developers, leading to innovation in energy storage and conversion materials.”

The paper, “Dual-Band Electrochromism in Hydrous Tungsten Oxide,” is published in the journal ACS Photonics. First author of the paper is Jenelle Fortunato, a postdoctoral researcher at NC State. The paper was co-authored by Noah Holzapfel, a postdoctoral researcher at NC State; Matthew Chagnot, a Ph.D. student at NC State; James Mitchell, a recent Ph.D. graduate of NC State; Benjamin Zydlewski and Hsin-Che Lu of the University of Texas at Austin; and Ming Lei and De-en Jiang of Vanderbilt University.

The research was done with support from the National Science Foundation, under grant 1653827; the U.S. Department of Energy’s Office of Science, under grant DE-SC0023408; and the Welch Foundation, under grant F-1848.

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Note to Editors: The study abstract follows.

“Dual-Band Electrochromism in Hydrous Tungsten Oxide”

Authors: Jenelle Fortunato, Noah P. Holzapfel, Matthew Chagnot, James B. Mitchell, and Veronica Augustyn, North Carolina State University; Benjamin Z. Zydlewski, Hsin-Che Lu, and Delia J. Milliron, University of Texas at Austin; Ming Lei and De-en Jiang, Vanderbilt University

Published: Sept. 1, ACS Photonics

DOI: 10.1021/acsphotonics.3c00921

Abstract: The independent modulation of visible and near-infrared light by a single material, termed dual-band electrochromism, is highly desirable for smart windows to enhance the energy efficiency of buildings. Tungsten oxides are commercially important electrochromic materials, exhibiting reversible visible and near-infrared absorption when electrochemically reduced in an electrolyte containing small cations or protons. The presence of structural water in tungsten oxides has been associated with faster electrochromic switching speeds. Here, we find that WO₃·H₂O, a crystalline hydrate, exhibits dual-band electrochromism unlike the anhydrous WO₃. This provides a heretofore unexplored route to tune the electrochromic response of tungsten oxides. Absorption of near-infrared light is achieved at low Li⁺/e^– injection, followed by the absorption of visible light at higher Li⁺/e^– injection as a result of an electrochemically induced phase transition. We propose that the dual-band modulation is possible due to the more open structure of WO₃·H₂O as compared to WO₃. This facilitates a more extended solid-solution Li⁺ insertion regime that benefits the modulation of near-infrared radiation via plasmon absorption. Higher degrees of Li⁺/e^– insertion lead to polaronic absorption associated with localized charge storage. These results inform how structural factors influence the electrochemically induced spectral response of transition-metal oxides and the important role of structural water beyond optical switching speed.